Publication:
The synthesis and complex-formation of dibenzo[e,k]-2,3-bis (hydroxyimino)-1,4,7,10-tetraaza-2,3,8,9-tetrahydrocyclododecine

dc.contributor.buuauthorBekaroğlu, Özer
dc.contributor.buuauthorBank, Cengiz
dc.contributor.departmentMühendislik Fakültesi
dc.contributor.orcid0000-0002-9249-2385tr_TR
dc.contributor.researcheridN-9731-2013tr_TR
dc.date.accessioned2021-06-29T07:37:14Z
dc.date.available2021-06-29T07:37:14Z
dc.date.issued1983
dc.description.abstractDibenzo[e,k]-2,3-bis(hydroxyimino)-1,4,7,10-tetraaza-2,3,8,9-tetrahydrocyclododecine(LH4) has been prepared from anti-dichloro-glyoxime, 1,2-bis(o-amino-phenylamino)ethane, and sodium bicarbonate in ethanol. The structure of this dioxime is found to be in anti-form according to 1H-n.m.r. and i.r. spectral data. LH4 gives trinuclear complexes [(LH)2M3] with Cu(II), Ni(II), Co(II), Pd(II), and UO2(VI) by coordinating through N atoms in both aza and oxime groups. In [(LH3)Cl(C2O)Zn], a six-membered chelate ring has been formed. A mononuclear Pd(II) complex has been also isolated at room temperature. 1H-nuclear magnetic resonance, i.r., and u.v.-visible data are given.en_US
dc.identifier.citationBank, C. ve Bekaroğlu,Ö. (1983). ''The synthesis and complex-formation of dibenzo[e,k]-2,3-bis (hydroxyimino)-1,4,7,10-tetraaza-2,3,8,9-tetrahydrocyclododecine''. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 13(8), 1047-1058.tr_TR
dc.identifier.endpage1058tr_TR
dc.identifier.issn0094-5714
dc.identifier.issue8tr_TR
dc.identifier.scopus2-s2.0-84953476312tr_TR
dc.identifier.startpage1047tr_TR
dc.identifier.urihttps://doi.org/10.1080/00945718308071337
dc.identifier.urihttp://hdl.handle.net/11452/20889
dc.identifier.volume13tr_TR
dc.identifier.wosA1983SJ46000008
dc.indexed.scopusScopusen_US
dc.indexed.wosSCIEen_US
dc.language.isoenen_US
dc.publisherMarcel Dekker Incen_US
dc.relation.journalSynthesis and reactivity in inorganic and metal-organic chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergitr_TR
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectChemistryen_US
dc.subject.wosChemistry, inorganic & nuclearen_US
dc.titleThe synthesis and complex-formation of dibenzo[e,k]-2,3-bis (hydroxyimino)-1,4,7,10-tetraaza-2,3,8,9-tetrahydrocyclododecineen_US
dc.typeArticle
dspace.entity.typePublication
local.contributor.departmentMühendislik Fakültesitr_TR
local.indexed.atWOS

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