Publication: 5,5-diethylbarbiturate complexes of silver with 2,2 '-bipyridine and 3-(2-pyridyl)propanol: Syntheses, crystal structures, spectroscopic, thermal and antimicrobial activity studies
dc.contributor.author | Karakaya, Haydar | |
dc.contributor.author | Yılmaz, Fatih | |
dc.contributor.author | Büyükgüngör, Orhan | |
dc.contributor.buuauthor | Yılmaz, Veysel Turan | |
dc.contributor.department | Fen Edebiyat Fakültesi | |
dc.contributor.department | Kimya Bölümü | |
dc.contributor.orcid | 0000-0002-2849-3332 | tr_TR |
dc.contributor.researcherid | L-7238-2018 | tr_TR |
dc.contributor.scopusid | 7006269202 | tr_TR |
dc.date.accessioned | 2022-06-23T13:14:14Z | |
dc.date.available | 2022-06-23T13:14:14Z | |
dc.date.issued | 2008-02 | |
dc.description.abstract | Two silver 5,5-diethylbarbiturate (barb) complexes with 2,2'-bipyridine (bpy) and 3-(2-pyridyl) propanol (pypr), [Ag(barb)(bpy)] (1) and [Ag(barb)(pypr)] (2), have been prepared and characterized by elemental analysis, IR spectroscopy, thermal analysis, and single crystal X-ray diffraction. Both complexes crystallize in the triclinic space group P (1) over bar with Z = 2. The barb ligand in 1 is N-coordinated and the bpy ligand acts as a bichelating ligand leading to an AgN3 tricoordination. Crystals of 1 feature a three-dimensional network based on N-H center dot center dot center dot O hydrogen bonding, pi(bpy)center dot center dot center dot pi(bpy), C-H center dot center dot center dot pi(bpy) and pi(bpy)-Ag interactions. In 2, the pypr and barb ligands behave as monodentate ligands through their N atoms, forming a distorted linear AgN2 coordination. Molecules of 2 are doubly bridged by N-H center dot center dot center dot O hydrogen bonds and further connected via O-H center dot center dot center dot O hydrogen bonds and aromatic pi(pypr)center dot center dot center dot pi(pypr) stacking interactions into a supramolecular network. Both complexes exhibit similar thermal decomposition behavior in air. The first stage corresponds to removal of the co-ligands such as bpy or pypr while the degradation of the barb moiety occurs at higher temperatures to give Ag2O. Like the barb, bpy and pypr ligands, 2 does not show any significant antimicrobial activity, but 1 is active against bacteria and fungi. | en_US |
dc.identifier.citation | Yılmaz, F. vd. (2008). "5,5-diethylbarbiturate complexes of silver with 2,2 '-bipyridine and 3-(2-pyridyl)propanol: Syntheses, crystal structures, spectroscopic, thermal and antimicrobial activity studies". Zeitschrift fur Naturforschung Section B-AJournal of Chemical Sciences, 63(2), 134-138. | en_US |
dc.identifier.endpage | 138 | tr_TR |
dc.identifier.issn | 0932-0776 | |
dc.identifier.issue | 2 | tr_TR |
dc.identifier.scopus | 2-s2.0-39449107263 | tr_TR |
dc.identifier.startpage | 134 | tr_TR |
dc.identifier.uri | https://doi.org/10.1515/znb-2008-0204 | |
dc.identifier.uri | https://www.degruyter.com/document/doi/10.1515/znb-2008-0204/html | |
dc.identifier.uri | http://hdl.handle.net/11452/27377 | |
dc.identifier.volume | 63 | tr_TR |
dc.identifier.wos | 000253003200004 | |
dc.indexed.wos | SCIE | en_US |
dc.language.iso | en | en_US |
dc.publisher | Walter de Gruyter Gmbh | de |
dc.relation.collaboration | Yurt içi | tr_TR |
dc.relation.journal | Zeitschrift fur Naturforschung Section B-A Journal of Chemical Sciences | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi | tr_TR |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | 2,2′-dipyridine | en_US |
dc.subject | 3-(2-pyridyl)propanol | en_US |
dc.subject | 5,5-diethylbarbiturate | en_US |
dc.subject | Crystal structure | en_US |
dc.subject | Silver(i) | en_US |
dc.subject | Chromium compounds | en_US |
dc.subject | Complex networks | en_US |
dc.subject | Complexation | en_US |
dc.subject | Ligands | en_US |
dc.subject | Microorganisms | en_US |
dc.subject | Propanol | en_US |
dc.subject | Silver metallography | en_US |
dc.subject | Silver oxides | en_US |
dc.subject | Single crystals | en_US |
dc.subject | Synthesis (chemical) | en_US |
dc.subject | Thermoanalysis | en_US |
dc.subject | Anti-microbial activity | en_US |
dc.subject | Dipyridine | en_US |
dc.subject | Single crystal x-ray diffraction | en_US |
dc.subject | Supramolecular networks | en_US |
dc.subject | Thermal decomposition behavior | en_US |
dc.subject | Three-dimensional networks | en_US |
dc.subject | Hydrogen bonds | en_US |
dc.subject | Copper(ıı) | en_US |
dc.subject | 2-Pyridinepropanol | en_US |
dc.subject | Spectra | en_US |
dc.subject | Ligands | en_US |
dc.subject | Zinc | en_US |
dc.subject.scopus | Thiobarbituric Acid; Barbiturates; DMV | en_US |
dc.subject.wos | Chemistry, inorganic & nuclear | en_US |
dc.subject.wos | Chemistry, organic | en_US |
dc.title | 5,5-diethylbarbiturate complexes of silver with 2,2 '-bipyridine and 3-(2-pyridyl)propanol: Syntheses, crystal structures, spectroscopic, thermal and antimicrobial activity studies | en_US |
dc.type | Article | |
dc.wos.quartile | Q3 (Chemistry, inorganic & nuclear) | en_US |
dc.wos.quartile | Q4 (Chemistry, organic) | en_US |
dspace.entity.type | Publication | |
local.contributor.department | Fen Edebiyat Fakültesi/Kimya Bölümü | tr_TR |
local.indexed.at | Scopus |
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